首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1293篇
  免费   450篇
  国内免费   108篇
化学   244篇
晶体学   27篇
力学   65篇
综合类   42篇
数学   282篇
物理学   1191篇
  2023年   9篇
  2022年   38篇
  2021年   22篇
  2020年   38篇
  2019年   28篇
  2018年   32篇
  2017年   46篇
  2016年   51篇
  2015年   40篇
  2014年   105篇
  2013年   107篇
  2012年   110篇
  2011年   131篇
  2010年   121篇
  2009年   104篇
  2008年   136篇
  2007年   114篇
  2006年   107篇
  2005年   66篇
  2004年   65篇
  2003年   78篇
  2002年   59篇
  2001年   42篇
  2000年   25篇
  1999年   25篇
  1998年   32篇
  1997年   26篇
  1996年   20篇
  1995年   11篇
  1994年   13篇
  1993年   5篇
  1992年   6篇
  1991年   5篇
  1990年   4篇
  1989年   5篇
  1988年   1篇
  1987年   4篇
  1986年   2篇
  1985年   2篇
  1984年   2篇
  1982年   1篇
  1980年   2篇
  1979年   8篇
  1977年   1篇
  1976年   1篇
  1974年   1篇
排序方式: 共有1851条查询结果,搜索用时 15 毫秒
11.
Let G be a 5‐connected triangulation of a surface Σ different from the sphere, and let be the Euler characteristic of Σ. Suppose that with even and M and N are two matchings in of sizes m and n respectively such that . It is shown that if the pairwise distance between any two elements of is at least five and the face‐width of the embedding of G in Σ is at least , then there is a perfect matching M0 in containing M such that .  相似文献   
12.
We described the design and synthesis of a colorimetric and ratiometric fluorescent probe based on a conjugated π-electron system that displayed differential fluorescence responses towards cyanide and sulfide and demonstrated its utility in intracellular ion imaging and logic gate.  相似文献   
13.
《Electrophoresis》2017,38(3-4):507-512
LIF detection often requires labeling of analytes with fluorophores; and fast fluorescent derivatization is valuable for high‐throughput analysis with flow‐gated CE. Here, we report a fast fluorescein‐labeling scheme for amino acid neurotransmitters, which were then rapidly separated and detected in flow‐gated CE. This scheme was based on the reaction between primary amines and o‐phthalaldehyde in the presence of a fluorescent thiol, 2‐((5‐fluoresceinyl)aminocarbonyl)ethyl mercaptan (FACE‐SH). The short reaction time (<30 s) was suited for on‐line mixing and derivatization that was directly coupled with flow‐gated CE for rapid electrophoretic separation and sensitive LIF detection. To maintain the effective concentration of reactive FACE‐SH, Tris(2‐carboxyethyl)phosphine was added to the derivatization reagents to prevent thiol loss due to oxidation. This labeling scheme was applied to the detection of neurotransmitters by coupling in vitro microdialysis with online derivatization and flow‐gated CE. It is also anticipated that this fluorophore tagging scheme would be valuable for on‐chip labeling of proteins retained on support in SPE.  相似文献   
14.
15.
Solid-stated smart polymers responsive to external stimuli have attracted much attention for potential application in the field of photoelectron devices, logic gates, sensor, data storage and security. However, it is a bigger challenge for polymers than that for small molecules in solid state to acquire stimuli-responsive properties, because polymers with high molecular weight are not as easy to change the packing structure as small molecules under external stimulation. Here, a D-A type alternating copolymer PTMF-o containing 3,4-bisthienylmaleimide(A unit) and fluorene(D unit) is designed and synthesized. Upon irradiation of sunlight, PTMF-o film exhibits a photo-response with the color altering from purple to colorless. It is attributed to the structure of copolymer transformed from ring-opening form(PTMF-o) to ring-closure form(PTMF-c), resulting from the oxidative photocyclization of 3,4-bisthienylmaleimide unit. Consequently, the ability of charge transfer(CT) from fluorene to 3,4-bisthienylmaleimide unit in PTMF-o can be easily weakened by light stimuli. PTMF-o film displays a WORM-type resistive storage performance for the strong CT. Interestingly, after exposure, the electrical memory behavior in situ transfers into FLASH type, due to weak CT in PTMF-c. PTMF-o film can also be employed as smart material to construct NAND and NOR logic gates by using light as input condition. The work provides a simple way to modify the electronic properties of polymers and realize stimuli-response in solid states.  相似文献   
16.
Modeling of terrain impact caused by tracked vehicles   总被引:1,自引:0,他引:1  
Analytical models that can predict the terrain impact caused by tracked vehicles on a horizontal plane were developed and tested. The models included a disturbed width model and an impact severity model. Inputs of the terrain impact models included vehicle static properties, vehicle dynamic properties, and terrain properties. The tested vehicles included an M1A1 tank, an M577 Armored Personal Carrier (APC), and an M548 cargo carrier. The models were verified with field tests conducted in Yakima Training Center in Yakima, WA, Fort Riley, KS, and Camp Atterbury, Indiana. The average percentage errors of the disturbed width model for the M1A1, M577, and the M548 were 10.0%, 27.3%, and 8.5%, respectively. The average percentage errors of the impact severity model of the M1A1 and M577 were 25.0% and 21.4%, respectively.  相似文献   
17.
“门控制”效应分子印迹传感器测定绿麦隆   总被引:1,自引:0,他引:1  
在氧化铂电极表面采用化学聚合法制得绿麦隆分子印迹膜传感器。利用"门控制"中"门"的数量变化控制催化性能的强弱,结合氧化铂对过氧化氢的催化放大效应,有效的提高了传感器的灵敏度并建立了对环境中绿麦隆残留的检测方法。研究了氧化铂电极对过氧化氢的催化效果,并对分子印迹膜聚合配比、过氧化氢浓度、洗脱时间、重吸附时间进行优化。在优化条件下,绿麦隆浓度在1.0×10-88.0×10-6mol/L范围内与氧化铂电极对过氧化氢的催化电流呈负相关性,检出限为5.4×10-9moL/L。该传感器成功应用于农田水样的检测,其回收率为98.5%102.0%。  相似文献   
18.
19.
Full field laser Doppler imaging (LDI) and single exposure laser speckle contrast imaging (LSCI) are directly compared using a novel instrument which can concurrently image blood flow using both LDI and LSCI signal processing. Incorporating a commercial CMOS camera chip and a field programmable gate array (FPGA) the flow images of LDI and the contrast maps of LSCI are simultaneously processed by utilizing the same detected optical signals. The comparison was carried out by imaging a rotating diffuser. LDI has a linear response to the velocity. In contrast, LSCI is exposure time dependent and does not provide a linear response in the presence of static speckle. It is also demonstrated that the relationship between LDI and LSCI can be related through a power law which depends on the exposure time of LSCI.  相似文献   
20.
通过对线间电容耦合模型的研究, 提出了一种基于互连线电容耦合的SR锁存电路设计方案. 该方案首先分析互连线间电容耦合关系, 利用MOS管栅极电容模拟互连线电容; 然后利用电容耦合结构与线计算特性, 设计或非逻辑门电路, 在此基础上实现基于互连线电容耦合的SR锁存电路; 最后在TSMC 65nm Spectre环境下仿真验证. 结果表明 所设计的电路逻辑功能正 确, 且具有低硬件开销特性.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号